DOW Glycol Ether products, as well as the materials to manufacture them, are produced to exacting standards. Methyl CARBITOL solvent is suitable for dyes, oils, fats, waxes and resins. Measured value determined by chemical oxygen demand procedure published in Standard Methods for the Examination of Water and Wastewater, 18th ed, Am Public Health Assoc., Washington, DC (1992). Applications ®TMTrademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow 324-06467-0716-BDC. DOW Glycol Ether products do not present a significant flammability hazard. (3) Percent by weight; 75% Hexyl CARBITOL solvent: 25% water (solubility limitations). It attacks some forms of plastics, rubber and coatings. Hexyl CARBITOL solvent is useful as a coalescing aid in waterborne emulsion or dispersion coatings. Soluble in tetrachloromethane. Methyl CARBITOL Solvent (Diethylene Glycol Monomethyl Ether). Such treatments should remove solvent residues that could be considered food additives. Registration dossier . Table 4. (2) OECD Guidelines for Testing of Chemicals, Organization for Economic Cooperation and Development, Vol. IDENTIFICATION MSDS Name: Diethylene Glycol Monobutyl Ether Synonyms: Butyl Carbitol, Glycol Ether DB, Butyl Di Glycol 2. Our blogs contain information on chemicals and food additives, including nutritional supplements, personal care ingredients, sanitation chemicals, and technical-grade chemicals. Biodegradation testing was conducted following methods published by the Environmental Protection Agency (EPA)(1) and Organization for Economic Cooperation and Development (OECD)(2). Belongs to the Following Reactive Group(s) Alcohols and Polyols; Ethers; Potentially Incompatible Absorbents. Glycol ether EB . Glycol Ether (EB) can solvate both water-soluble and hydrophobic materials. The linear hexyl portion of Hexyl CELLOSOLVE solvent provides excellent oil solubility characteristics that make it useful in both consumer and industrial cleaner applications. Butyl CARBITOL solvent is used as a solvent in formulating aids for latex paints and as a dispersant for vinyl chloride resins used in organosols. Butyl CELLOSOLVE solvent is an excellent solvent widely used in coatings and cleaner applications, including many directed to consumer markets. Mutual Solubility of Butyl CELLOSOLVE Solvent/Water vs. It is liable to form peroxides on exposure to air and light. Related applications include special coatings for polystyrene, epoxy coatings and high-low thinners for viscosity reduction of alkyd baking enamels. You’ve likely encountered these chemicals — from glycol ether EB to glycol ether DB — in countless industrial applications. (1) Percent by weight; 25% Product: 75% water. Butyl CELLOSOLVE solvent exhibits strong solvency for alkyd, phenolic, nitrocellulose and maleic-modified resins. Hexyl CELLOSOLVE solvent has the characteristic structure of glycol ethers and contains both ether and alcohol functional groups in the same molecule. As a dispersant, it prevents congealing, which aids … 2, Section 3, Degradation and Accumulation, Updated 1993. Glycol Ether EB is popular because it’s used for multiple things like cleaning products, herbicides, oil … It improves penetrating and wetting action of phosphoric acid-type rust removers. Hexyl CELLOSOLVE solvent is a high boiling point, slow evaporating solvent with excellent solvency characteristics. Several glycol ethers have been cleared by the Environmental Protection Agency (EPA) for use as inert ingredients in pesticide formulations under EPA Regulation 40 CFR 180.1001. Component of defoaming agents used in the manufacture of paper and paperboard. What’s actually in the chemical, though? Heating the aqueous EB extract solution to 55 °C formed two liquid phases: a glycol ether‐rich phase and an aqueous product phase containing the great majority of the product protein. The product line consists of more than 10 distinct chemicals. Hexyl CARBITOL solvent, like Hexyl CELLOSOLVE solvent, displays a strong hydrocarbon-type solvency. Butyl CELLOSOLVE solvent heightens gloss, improves flow-out and prevents orange-peel formation in lacquers, conventional and high solid coatings. (3) EPA/ASTM bioassay procedures were followed in obtaining these values. 58 / Monday, March 26, 2012 / Rules and Regulations 02/13/2018 EN (English US) 5/8 Solubility : Soluble in water. Glycolether sind eine Stoffgruppe organischer Chemikalien, die auf Ethylenglycol oder Diethylenglycol als Basiseinheit basieren. | Privacy. Information On Glycol Ether From Wikipedia Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. Ethylene glycol ethers and glycol ether acetates are clear liquids with mild, pleasant odors. † The physical property data listed are considered to be typical properties, not specifications. Before handling any other products mentioned in the text, you should obtain available product safety information and take necessary steps to ensure safety of use. OECD 301-B Carbon Dioxide Evolution Biodegradation Testing(1). Surface Tension of Aqueous Solutions for Selected CELLOSOLVE Solvents, Figure 2. After the original test time, each retest should be one-half the original period. Typically, e-series glycol ethers are found in pharmaceuticals, sunscreens, cosmetics, inks, dyes and water-based paints, while p-series glycol ethers are used in degreasers, cleaners, aerosol paints and adhesives. Soluble in ether. Due to the presence of both an ether and a hydroxyl group in the same molecule, these products are miscible in water, as well as most organic solvents. CARBITOL solvent is an important solvent in non-grain-raising wood stains and serves as a component of industrial cleaners. Additive to flume water for washing sugar beets prior to the slicing operation at a level not to exceed 1 ppm. Some typical examples are: Propyl CELLOSOLVE Solvent (Ethylene Glycol Monopropyl Ether). The Dow Chemical Company is the world’s leading producer of ethylene-oxide-based glycol ethers, both in product-line breadth and total volume produced. Glycol ethers have relatively low viscosities and freezing points. As a result, it provides unique cleaning power for removal of both watersoluble and greasy (water-insoluble) soils. Surface Tension of Aqueous Solutions for Selected CARBITOL Solvents, Figure 3. LT313-1000 . The broader glycol ether category covers a specific group of solvents made from alkyl ethers of ethylene glycol or propylene glycol. Properties of Glycol Ethers Considering 200-500 kilotons of glycol ether are produced annually, chances are your business depends on this United States high-production volume chemical (a chemical whose production exceeds 100 kilotons a year) to keep it running smoothly. Foam in fire extinguishers, oil spill dispersants, asphalt release products, degreasers, and varnish removers are a wide array of products that use glycol ether EB as a solvent. EPA Status The alkoxytriglycols are useful as low-volatility components in paint stripping formulations, as dye carriers for textile dye processes, as chemical process solvents and as intermediates for making esters for use as solvents, surfactants and plasticizers. Health Hazards: Irritating to Eyes Safety Hazard: Not classified as FLAMMABLE, but will burn HEALTH HAZARD: Skin Contact: May cause moderate irritation to skin. Glycol ethers are either "e-series" or "p-series" glycol ethers, depending on whether they are made from ethylene oxide or propylene oxide, respectively. Stainless steel or high baked, phenolic-lined tanks may be used for critical applications sensitive to slight discoloration or trace-iron contamination. In fabric cleaners, Butyl CELLOSOLVE solvent assists in removing water-soluble stains and aids in brightening the colors of garments. Due to its slow evaporation and excellent solvency characteristics, Hexyl CARBITOL solvent contributes good flow and leveling to high solids coatings during the drying/curing cycle. Glycol Ether is typical used in most industrial applications as a surfactant. (5) EPA, CFR 797.1400, Fish Acute Toxicity Test, February 1997. Since government regulations and use conditions are subject to change, it is the user’s responsibility to determine that this information is appropriate and suitable under current, applicable laws and regulations. The petroleum industry relies on glycol ether EB as a drilling stabilizer, oil slick dispersant, and in water-based and oil-based fracturing fluids. Ethylene glycol monobutyl ether, more commonly known as glycol ether EB, butoxyethanol, or 2-Butoxyethanol, is an organic compound with the chemical formula BuOC2H4OH with a sweet odor reminiscent of its family line of ethers. This glycol ether is incorporated in high-bake enamels to contribute desirable flow and gloss characteristics. Eastman™ EB Acetate (Ethylene Glycol Monobutyl Ether Acetate) is a high boiling glycol ether-ester. Environmental Effects Ecological Effects of Selected Glycol Ethers. These solvents typically have a higher boiling point, together with the favorable solvent properties of … (1) This EPA Regulation cross-references to FDA Regulation 182.99 and 582.99 (21 CFR). Selected DOW Glycol Ether Products. Thousands of industries rely on glycol ether EB. (2) Pour Point. The use of glycol ethers also allowed exploitation of temperature‐change‐induced phase splitting behavior to concentrate the desired product. This feature can be used to enhance the solvent effect of Butyl CELLOSOLVE solvent in aqueous solutions. (1) Fate, Transport, and Transformation Test Guidelines, OPPTS 835.3110, Ready Biodegradability, EPA 712-C-98-076, January 1998. Liquid. Hexyl CARBITOL solvent is used in metal deco inks as a slow evaporating solvent providing good flow and leveling. Dow requests that the customer read, understand, and comply with the information contained in this publication and the current Material Safety Data Sheet(s). HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, colourless WARNING! Precautionary statements : Prevention : P210 Keep away from heat/sparks/open flames/hot surfaces. Manufacturers of these chemicals are members of the Oxygen Solvents Producers Association (OSPA), a branch of the European Solvents Industry … (3) Alsop, G. M., R. A. Conway, “Bacterial Growth Inhibition Test,” Journal Water Pollution Control Federation, Vol. The petroleum industry relies on glycol ether EB as a drilling stabilizer, oil slick dispersant, and in water-based and oil-based fracturing fluids. Small quantities of CARBITOL solvent in these mixtures form translucent-to-clear dispersions, in contrast to the usual turbid dispersion that indicates incomplete solubility. The most common application for EB is used for is in paints and surface coatings as a surfactant and solvent. Glycol Ether EB is a solvent used in a wide range of industries. Glycol ethers are selected for specific purposes, suc… Shipment of these products must comply with all applicable Federal, state and local regulations. Dow has carried out a series of laboratory studies on the biodegradation and ecological effects of its glycol ethers. Butyl CARBITOL Solvent (Diethylene Glycol Monobutyl Ether). For several of the products, special Health Effects Overviews and Toxicology Summaries have been prepared. Closed containers may explode due to … Glycol Ether EB is affordably priced solvent that can dissolve both hydrophobic and water soluble compounds, and is a solvent for paints, inks, cleaning products. Butyl CARBITOL solvent is a dye solvent used to promote rapid and uniform ink penetration for printing box-board and similar materials. Ethoxytriglycol is a possible exception, since it freezes at -9°F (-23°C). Glycol Ether EB Safety Data Sheet according to Federal Register / Vol. Soluble in heptane. The product’s mild odor and ability to improve dye penetration make it attractive for non-grain-raising wood stains, spirit-type dyes and textile dye pastes. As a dispersant, it prevents congealing, which aids in the release of gas. This varies based on the type of coating or paint. Some brand names for glycol ethers include Cellosolve, R Carbitol, R Dowanol, R and Ektasolve. Glycol Ether DB Safety Data Sheet according to Federal Register / Vol. Acute (short-term) exposure to high levels of the glycol ethers in humans results in narcosis, pulmonary edema, and severe liver and kidney damage. LT313-4440 . Mild-odored solvents for many resins, oils, waxes, fats and dyestuffs, Coupling agents for many water/organic systems, Miscible with a wide range of polar and non-polar organic solvents, Dye solvents in the textile, leather and printing industries, Solvents for grease and grime in industrial cleaning and specialty formulations, Solvents for insecticides and herbicides for agricultural applications, Coupling solvents for hard-surface cleaners and other soap-hydrocarbon systems, Solvents and cosolvents for conventional lacquer, enamel and stains for industrial coating systems, Cosolvents for waterborne industrial coating systems, Reaction with carboxylic acids, carboxylic acid chlorides, anhydrides and inorganic acids to produce esters, Reaction with organic halides to produce ethers, such as glymes, Reaction with alkenes and alkynes to produce ethers, Reaction with halogenating agents to produce alkoxy alkyl halides, Reaction with epoxides to produce polyether alcohols, Reaction with aldehydes and ketones to produce hemiacetals and acetals. The size of the shipment, mode of transportation and latest regulations all affect shipping classifications. (2) Percent by weight; 90% Hexyl CELLOSOLVE solvent: 10% water (solubility limitations). FDA Status    – Inverse Solubility, Storage & Handling If there are no residues that … Figure 1. (7) Annual Book of ASTM Standards, Water and Environmental Technology, Vol.11.05, (1995). Inert (or occasionally active) ingredients for use in formulations applied to growing crops only up to time of harvest. C&L Inventory . Shipping Data Methoxytriglycol (Triethylene Glycol Monomethyl Ether), Ethoxytriglycol (Triethylene Glycol Monoethyl Ether), Butoxytriglycol (Triethylene Glycol Monobutyl Ether). Contact the industrial chemical supplier, Bell Chem, today at 407-339-2355 (BELL) to speak with one of our representatives concerning glycol ether EB or any of our other industrial chemicals. Your business can undoubtedly use it as a safe, effective dispersant and solvent as well. Butyl CARBITOL solvent is useful in lacquers, dopes and stamp-pad and printing inks that require a solvent with an extremely low rate of evaporation. No smoking. When considering the use of any Dow products in a particular application, you should review Dow’s latest Material Safety Data Sheets and ensure that the use you intend can be accomplished safely. (4) Methods for Measuring the Acute Toxicity of Effluents to Freshwater and Marine Organisms, EPA/600/4-85/O1 3, March 1985 Eastman EB Solvent (Ethylene Glycol Monobutyl Ether) offers numerous benefits in coating, ink, and cleaner applications. The customer should furnish the information in this publication to its employees, contractors, and customers, or any other users of the product(s), and request that they do the same. Diethylene Glycol Butyl Ether Product Page. Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. As a solvent, glycol ether is an ingredient in many coatings, including latex paints, resins, lacquers, varnishes, and enamels. COMBUSTIBLE LIQUID AND VAPOR. Propyl CELLOSOLVE solvent is useful in printing and other specialized coatings applications. It is used in household cleaners, liquid soaps, cosmetics spray lacquers, enamels, herbicides, hydraulic fluids, fabric dyes and inks, household degreasers, dry-cleaning substances, and latex paints. MAY BE HARMFUL IF … Glycol Ether EB has excellent solvency for a variety of resins including acrylic, alkyd, phenolic, epoxy, nitrocellulose and urethane resins. Soluble in oil. Figure 6. It is an excellent solvent for household and industrial cleaners, rust removers, and disinfectant. Registration dossier . R Your Right to Know: A product may contain a glycol ether without listing it on the label or in the ingredients. Glycol ether’s unique chemical structure of an alcohol and an ether give it hydrophobic and water soluble properties. These solvents typically have a higher boiling point, together with the favorable solvent properties of lower-molecular weight ethers and alcohols. Hexyl CARBITOL Solvent (Diethylene Glycol Monohexyl Ether). … ApplicationsUsed in a variety of cleaning applications such as household cleaners, industrial cleaners, laundry prewash stain. Hexyl CELLOSOLVE Solvent (Ethylene Glycol Monohexyl Ether). It is extremely important that the last solvent to evaporate has good solvency properties for the coating system. Als Lösungsmittel haben Glycolether typischerweise die vorteilhaften Lösungsmitteleigenschaften von Ethern und Alkoholen niedrigerer Molekülmassen, jedoch höhere Siedepunkte, was für die Verarbeitung vorteilhaft ist. Glycol Ethers are a family of chemicals with key solvent properties used in various and diverse applications. Introduction Thus, glycol ethers produced from higher molecular weight alcohols, such as Hexyl CELLOSOLVE™ solvent, have limited water solubility. In addition, Butyl CELLOSOLVE solvent is the most widely used cosolvent for industrial waterborne coatings due to its excellent balance of volatility, resin solvency and oil/water solubility. In fact, glycol ether EB is the prime ingredient in hundreds of cleaning solutions used worldwide because of its ability to break down both hydrophilic and hydrophobic particles. Glycol Ethers Background. 77, No. (1) Pensky-Martens Closed Cup unless otherwise noted. © 2021  Merck KGaA, Darmstadt, Germany and/or its affiliates. Ethereal. After this time, material should be sampled and tests run to be sure that quality has been maintained. (1) This test method monitors carbon dioxide produced from the biooxidation of molecular carbon in the test substance. IZ180(N)LIQUID-1184 . † The physical property data listed are considered to be typical properties, not specifications. These substances are … Methyl and ethyl ethers of ethylene glycol are not used in consumer products in Europe. Both E-series glycol ethers and P-series glycol ethers can be used … KUV-5000(HARD COATING) Registration dossier . Hexyl CARBITOL solvent has shown excellent performance in cleaning formulation for the removal of greasy soils. Reproduction of any materials from the site is strictly forbidden without permission. Butyl rubber or EPDM can be used for gaskets and packing. CARBITOL Solvent (Diethylene Glycol Monoethyl Ether). Type in Product Names, Product Numbers, or CAS Numbers to see suggestions. Due to the presence of both an ether and a hydroxyl group in the same molecule, these products are miscible in water, as well as most organic solvents, making this group of products ideal for use as resin solvents in the paint and coating industry. Some glycol ethers exhibit an inverse solubility in water at elevated temperatures. Technical Service. Formulating with Glycol Ethers Article 1, Section 2, “Effects On Biotic Systems,” Updated 1993. HAZARDS IDENTIFICATION Appearance and Odor: Clear. According to the nature of alcohol, molecules of this class can be divided into two groups: E series and P series which correspond to ethylene and propylene respectively. These solvents are widely used paints & coatings, industrial cleaners, and inks. DOW Glycol Ether products are produced through continuous processes of selectively reacting an alcohol and ethylene oxide. Bacterial growth inhibition tests(3) indicate that none of the DOW Glycol Ether products should be inhibitory to conventional biological wastewater treatment processes at reasonable discharge levels [500 to 1000 mg/L in compliance with applicable regulations], and they would be expected to undergo rapid biodegradation in the concentrated biomass of these systems. They have relatively low vapor pressures.    – Vapor Pressure Curves It is partly water soluble and miscible with most organic solvents. 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